Extraction-absorptiometric determination of copper (II) with 4-(2-pyridylazo)-resorcin
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چکیده
منابع مشابه
Solvent extraction and separation of lanthanoids with mixtures of chelating extractant and 4-(2-pyridylazo)-resorcin
The solvent extraction of trivalent lanthanoids (La, Nd, Eu, Ho, and Lu) with mixtures of the chelating extractant 1-(2-thienyl)-4,4,4-trifluoro-1,3-butanedione (thenoyltrifluoro-acetone, HTTA) or 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-on (HP) and 4-(2-pyridylazo)-resorcin (PAR, S) in CHCl3 was studied. It was found that in the presence of 4-(2-pyridylazo)-resorcin the lanthanoids were extra...
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often an important process in industry and chemical analysis. Liquid-membrane transport in which the extraction and stripping operations are combined in a single process reduces the solvent inventory requirement, and also allows the use of expensive and highly selective extractions, which otherwise would be uneconomic in solvent extractants. For these reasons, liquid-membrane transport has attr...
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An extraction-spectrophotometric method for the determination of traces of copper (II) is described. The method is based on the quantitative extraction of copper as tetrabutylammonium tetrathiocyanato copper (II) into methyl isobutyl ketone, followed by spectrophotometric determination, using eriochrome black T as a metallochromic indicator. The red-violet mixed complex of copper absorbs at...
متن کاملSpectrophotometric determination of acidity constants of 4-(2-pyridylazo)resorcinol in binary methanol–water mixtures
The acidity constants of 4-(2-pyridylazo)resorcinol (PAR, Scheme 1) in binary mixtures of methanol–water at 25 ◦C and an ionic strength of 0.1 M have been determined spectrophotometrically. DATa ANalysis (DATAN) program applied for determination of acidity constants. As percent of methanol increases in solvent mixtures the pKa constants also increased. There is linear relationship between acidi...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1969
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.18.998